Mass Spectrometry Quiz

1.
Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?
- Francis William Aston
- Wolfgang Paul
- John Bennett Fenn
Your answer:

Correct answer:

Aston is a 44-kilometer lunar impact crater located along the northwestern limb of the Moon. The crater was named in honor of Francis W. Aston.
2.
Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?
- Electrical engineer
- Owner of an antiquarian bookshop
- Circus ringmaster
Your answer:

Correct answer:

His father, Joseph James Thomson, ran an antiquarian bookshop founded by Thomson’s great-grandfather. [Wikipedia]
3.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?
- Burnaby Munson and Frank H. Field
- Michael Barber
- Hans-Dieter Beckey
Your answer:

Correct answer:

Chemical ionization was discovered in the laboratories of the Humble Oil and Refining Company in Baytown, TX. Munson and Field’s seminal paper on chemical ionization was published in 1966. [https://doi.org/10.1021/ja00964a001]
4.
The first on-line coupling of gas chromatography to a mass spectrometer was reported in 1959. What type of spectrometer was used for this purpose?
- Double-focusing mass spectrometer
- Time-of-flight mass spectrometer
- Quadrupole mass spectrometer
Your answer:

Correct answer:

The first GC/MS experiments were carried out by Fred McLafferty and Roland Gohlke at Dow Chemical with Bill Wiley and Ian McLaren at Bendix Research Laboratories. They used a Bendix timeof- flight mass spectrometer, which had been commercially introduced in 1956. The instrument was fast enough to keep up with the changing output of the GC column.
5.
Which mass spectrometer was carried by the American spacecraft Viking 1 sent to the planet Mars in 1975?
- Double-focusing mass spectrometer
- Time-of-flight mass spectrometer
- Quadrupole mass spectrometer
Your answer:

Correct answer:

Viking 1 carried two mass spectrometers, both equipped with double-focusing analyzers and electron ionization sources. The first spectrometer with a Mattauch-Herzog geometry was designed by Alfred Nier; it was intended to analyze the upper atmosphere of Mars. The second one with a Nier- Johnson geometry was part of the GC/MS apparatus designed by Klaus Biemann. It was used to analyze the regolith and the atmosphere at the landing site.
6.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?
- Phosphorescence of willemite
- Darkening of a photographic plate
- Charge detection using an electrometer
Your answer:

Correct answer:

In the spectrographs used by Thomson until 1910, the rays of positive electricity were detected by the phosphorescence they produced on a willemite screen. The screen was made by grinding rare zinc mineral willemite into a fine powder. After shaking in alcohol, the suspension was allowed to deposit slowly on a glass plate. Later, a photographic plate inside the spectrograph was used for more sensitive detection.
7.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?
- 1868
- 1968
- 1989
Your answer:

Correct answer:

The solution of differential equations of this type came from the French mathematician Émile Léonard Mathieu (1835-1890), who studied the mechanical vibrations of the elliptical drumheads.
8.
What is the trajectory of a charged particle moving parallel to a uniform electric field in a vacuum?
- The particle follows a curved path and continues to follow this path until it forms a complete circle
- Neither the trajectory nor the velocity of the particle changes
- The particle either accelerates or decelerates, depending on the field direction and the particle charge sign
Your answer:

Correct answer:

If a positive charge is moving in the same direction as the electric field vector the particle's velocity will increase. If it is moving in the opposite direction it will decelerate. If a negative charge is moving in the same direction as the electric field vector the particle will decelerate. If it is moving in the opposite direction it will accelerate.
9.
Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?
- A. J. C. Nicholson
- F. W. McLafferty
- F. Tureček
Your answer:

Correct answer:

It was first reported by Australian A. J. C. Nicholson in 1954 (Trans. Faraday Soc. 50: 1067-1073). The reaction description was published five years later (Anal. Chem. 1959, 31: 82–87) by the American chemist Fred McLafferty, by whose name we now refer to the rearrangement (McLafferty rearrangement).
10.
What is the base peak in the mass spectrum?
- The peak with the greatest m/z value
- The peak from which fragments are formed
- The peak that has the greatest intensity
Your answer:

Correct answer:

The base peak is the peak with the greatest intensity among all peaks in the spectrum. The intensity of each peak in the spectrum is expressed as a percentage relative to the intensity of the base peak.

Mass Spectrometry Quiz

Mass Spectrometry Quiz

Thank you for taking our quiz!

1.
Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

2.
Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?

3.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

4.
The first on-line coupling of gas chromatography to a mass spectrometer was reported in 1959. What type of spectrometer was used for this purpose?

5.
Which mass spectrometer was carried by the American spacecraft Viking 1 sent to the planet Mars in 1975?

6.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

7.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

8.
What is the trajectory of a charged particle moving parallel to a uniform electric field in a vacuum?

9.
Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?

10.
What is the base peak in the mass spectrum?

Czech Museum
of Mass Spectrometry

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Mass Spectrometry Quiz

Mass Spectrometry Quiz

Thank you for taking our quiz!

1. Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

2. Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?

3. Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

4. The first on-line coupling of gas chromatography to a mass spectrometer was reported in 1959. What type of spectrometer was used for this purpose?

5. Which mass spectrometer was carried by the American spacecraft Viking 1 sent to the planet Mars in 1975?

6. What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

7. The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

8. What is the trajectory of a charged particle moving parallel to a uniform electric field in a vacuum?

9. Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?

10. What is the base peak in the mass spectrum?

Czech Museumof Mass Spectrometry

Our partners

1.
Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

2.
Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?

3.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

4.
The first on-line coupling of gas chromatography to a mass spectrometer was reported in 1959. What type of spectrometer was used for this purpose?

5.
Which mass spectrometer was carried by the American spacecraft Viking 1 sent to the planet Mars in 1975?

6.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

7.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

8.
What is the trajectory of a charged particle moving parallel to a uniform electric field in a vacuum?

9.
Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?

10.
What is the base peak in the mass spectrum?

Czech Museum
of Mass Spectrometry