Mass Spectrometry Quiz

1.
Josef Mattauch is known for the development of Mattauch-Herzog double-focusing mass spectrometer and his work on isotopes and atomic weights. His career is connected with the Kaiser Wilhelm Institute for Chemistry in Berlin. Do you know where he was born?
- Berlin, Germany
- Ostrava, Czechia
- Klosterneuburg, Austria
Your answer:

Correct answer:

Josef Mattauch was born in 1895 in the city of Mährisch Ostrau, in what is now the Czech Republic, then part of the Austrian-Hungarian Empire.
2.
Which element has the largest number of stable isotopes?
- Molybdenum
- Tin
- Ytterbium
Your answer:

Correct answer:

Naturally occurring tin is a mixture of its ten stable isotopes and they are found in the percentages as follows: ¹¹²Sn (1.0 %), ¹¹⁴Sn (0.7 %), ¹¹⁵Sn (0.3 %), ¹¹⁶Sn (14.5 %), ¹¹⁷Sn (7.7 %), ¹¹⁸Sn (24.2 %), ¹¹⁹Sn (8.6 %), ¹²⁰Sn (32.6 %), ¹²²Sn (4.6 %), and ¹²⁴Sn (5.8 %). Molybdenum has six stable isotopes, ytterbium seven.
3.
Who made molecular elephants fly?
- John B. Fenn
- Joseph J. Thomson
- W. and O. Wright
Your answer:

Correct answer:

John Fenn was awarded Nobel Prize in Chemistry in 2002 for his work related to electrospray ionization of biological macromolecules. His famous phrase, "we made elephants fly" refers to the ability of electrospray to generate gas-phase ions from big protein molecules.
4.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?
- 1868
- 1968
- 1989
Your answer:

Correct answer:

The solution of differential equations of this type came from the French mathematician Émile Léonard Mathieu (1835-1890), who studied the mechanical vibrations of the elliptical drumheads.
5.
Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:
- Gold
- Iridium
- Rhenium
Your answer:

Correct answer:

The International Prototype of the Kilogram was a cylinder with a height and diameter of 39 mm made of an alloy of 90% platinum and 10% iridium.
6.
How long would be a paper needed for printing a profile mass spectrum measured in the m/z 0 1000 range at a resolution of 50,000 at m/z 500 if the peaks were to be 1 mm wide at their half maximum? Let us consider a constant width of all peaks.
- 1 m
- 10 m
- 100 m
Your answer:

Correct answer:

The resolution can be expressed as (m/z)/Δ(m/z), where Δ (m/z) is the peak width at 50 % of its maximum. For a resolution of 50,000 at m/z 500, the value of Δ(m/z) is 0.01. If the Δ(m/z) is to correspond to 1 mm, then the total width of the spectral record equals 1000/0.01 mm, which is 100,000 mm, which is 100 m.
7.
What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?
- The particle follows a curved path and continues to follow this path until it forms a complete circle
- The particle follows a helical path
- The particle follows a straight line and accelerates
Your answer:

Correct answer:

The magnetic force is perpendicular to the velocity so that it does no work on the charged particle. The particle’s kinetic energy and speed thus remain constant. The direction of motion is affected but not the speed.
8.
List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).
- Hydrazine, oxygen, methanol
- Methanol, hydrazine, oxygen
- Oxygen, methanol, hydrazine
Your answer:

Correct answer:

The monoisotopic masses of these compounds are 31.989829 Da (oxygen), 32.026215 Da (methanol), and 32.037448 Da (hydrazine).
9.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?
- Burnaby Munson and Frank H. Field
- Michael Barber
- Hans-Dieter Beckey
Your answer:

Correct answer:

Chemical ionization was discovered in the laboratories of the Humble Oil and Refining Company in Baytown, TX. Munson and Field’s seminal paper on chemical ionization was published in 1966. [https://doi.org/10.1021/ja00964a001]
10.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?
- Phosphorescence of willemite
- Darkening of a photographic plate
- Charge detection using an electrometer
Your answer:

Correct answer:

In the spectrographs used by Thomson until 1910, the rays of positive electricity were detected by the phosphorescence they produced on a willemite screen. The screen was made by grinding rare zinc mineral willemite into a fine powder. After shaking in alcohol, the suspension was allowed to deposit slowly on a glass plate. Later, a photographic plate inside the spectrograph was used for more sensitive detection.

Mass Spectrometry Quiz

Mass Spectrometry Quiz

Thank you for taking our quiz!

1.
Josef Mattauch is known for the development of Mattauch-Herzog double-focusing mass spectrometer and his work on isotopes and atomic weights. His career is connected with the Kaiser Wilhelm Institute for Chemistry in Berlin. Do you know where he was born?

2.
Which element has the largest number of stable isotopes?

3.
Who made molecular elephants fly?

4.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

5.
Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:

6.
How long would be a paper needed for printing a profile mass spectrum measured in the m/z 0 1000 range at a resolution of 50,000 at m/z 500 if the peaks were to be 1 mm wide at their half maximum? Let us consider a constant width of all peaks.

7.
What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

8.
List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).

9.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

10.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

Czech Museum
of Mass Spectrometry

Our partners

Mass Spectrometry Quiz

Mass Spectrometry Quiz

Thank you for taking our quiz!

1. Josef Mattauch is known for the development of Mattauch-Herzog double-focusing mass spectrometer and his work on isotopes and atomic weights. His career is connected with the Kaiser Wilhelm Institute for Chemistry in Berlin. Do you know where he was born?

2. Which element has the largest number of stable isotopes?

3. Who made molecular elephants fly?

4. The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

5. Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:

6. How long would be a paper needed for printing a profile mass spectrum measured in the m/z 0 1000 range at a resolution of 50,000 at m/z 500 if the peaks were to be 1 mm wide at their half maximum? Let us consider a constant width of all peaks.

7. What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

8. List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).

9. Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

10. What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

Czech Museumof Mass Spectrometry

Our partners

1.
Josef Mattauch is known for the development of Mattauch-Herzog double-focusing mass spectrometer and his work on isotopes and atomic weights. His career is connected with the Kaiser Wilhelm Institute for Chemistry in Berlin. Do you know where he was born?

2.
Which element has the largest number of stable isotopes?

3.
Who made molecular elephants fly?

4.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

5.
Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:

6.
How long would be a paper needed for printing a profile mass spectrum measured in the m/z 0 1000 range at a resolution of 50,000 at m/z 500 if the peaks were to be 1 mm wide at their half maximum? Let us consider a constant width of all peaks.

7.
What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

8.
List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).

9.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

10.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

Czech Museum
of Mass Spectrometry