Mass Spectrometry Quiz

1.
Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:
- Gold
- Iridium
- Rhenium
Your answer:

Correct answer:

The International Prototype of the Kilogram was a cylinder with a height and diameter of 39 mm made of an alloy of 90% platinum and 10% iridium.
2.
Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?
- Francis William Aston
- Wolfgang Paul
- John Bennett Fenn
Your answer:

Correct answer:

Aston is a 44-kilometer lunar impact crater located along the northwestern limb of the Moon. The crater was named in honor of Francis W. Aston.
3.
List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).
- Hydrazine, oxygen, methanol
- Methanol, hydrazine, oxygen
- Oxygen, methanol, hydrazine
Your answer:

Correct answer:

The monoisotopic masses of these compounds are 31.989829 Da (oxygen), 32.026215 Da (methanol), and 32.037448 Da (hydrazine).
4.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?
- Phosphorescence of willemite
- Darkening of a photographic plate
- Charge detection using an electrometer
Your answer:

Correct answer:

In the spectrographs used by Thomson until 1910, the rays of positive electricity were detected by the phosphorescence they produced on a willemite screen. The screen was made by grinding rare zinc mineral willemite into a fine powder. After shaking in alcohol, the suspension was allowed to deposit slowly on a glass plate. Later, a photographic plate inside the spectrograph was used for more sensitive detection.
5.
Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?
- A. J. C. Nicholson
- F. W. McLafferty
- F. Tureček
Your answer:

Correct answer:

It was first reported by Australian A. J. C. Nicholson in 1954 (Trans. Faraday Soc. 50: 1067-1073). The reaction description was published five years later (Anal. Chem. 1959, 31: 82–87) by the American chemist Fred McLafferty, by whose name we now refer to the rearrangement (McLafferty rearrangement).
6.
Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?
- Electrical engineer
- Owner of an antiquarian bookshop
- Circus ringmaster
Your answer:

Correct answer:

His father, Joseph James Thomson, ran an antiquarian bookshop founded by Thomson’s great-grandfather. [Wikipedia]
7.
What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?
- The particle follows a curved path and continues to follow this path until it forms a complete circle
- The particle follows a helical path
- The particle follows a straight line and accelerates
Your answer:

Correct answer:

The magnetic force is perpendicular to the velocity so that it does no work on the charged particle. The particle’s kinetic energy and speed thus remain constant. The direction of motion is affected but not the speed.
8.
Which element has the largest number of stable isotopes?
- Molybdenum
- Tin
- Ytterbium
Your answer:

Correct answer:

Naturally occurring tin is a mixture of its ten stable isotopes and they are found in the percentages as follows: ¹¹²Sn (1.0 %), ¹¹⁴Sn (0.7 %), ¹¹⁵Sn (0.3 %), ¹¹⁶Sn (14.5 %), ¹¹⁷Sn (7.7 %), ¹¹⁸Sn (24.2 %), ¹¹⁹Sn (8.6 %), ¹²⁰Sn (32.6 %), ¹²²Sn (4.6 %), and ¹²⁴Sn (5.8 %). Molybdenum has six stable isotopes, ytterbium seven.
9.
Who built the first mass spectrometer in Czechia?
- Čermák, Hanuš, Jech, Cabicar
- Červinka, Dědek, Ferles
- Jára Cimrman
Your answer:

Correct answer:

The first mass spectrometer in the country was built in the Laboratory of Physical Chemistry of the Czechoslovak Academy of Sciences. Four young scientists, Vladimír Čermák, Vladimír Hanuš, Čestmír Jech and Josef Cabicar, took part in its construction. At the time of the post-war shortage, it was very difficult to find the necessary components; some parts originated from captured German military equipment. The mass spectrometer was of the Nier type with simple focusing and 60° magnetic field, pumped by a mercury diffusion pump. The device was completed after two years, in 1953. The construction of this instrument was an extraordinary achievement awarded a year later by the State Prize. [Z. Herman, Chem. Listy 104, 955, 2010]
10.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?
- 1868
- 1968
- 1989
Your answer:

Correct answer:

The solution of differential equations of this type came from the French mathematician Émile Léonard Mathieu (1835-1890), who studied the mechanical vibrations of the elliptical drumheads.

Mass Spectrometry Quiz

Mass Spectrometry Quiz

Thank you for taking our quiz!

1.
Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:

2.
Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

3.
List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).

4.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

5.
Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?

6.
Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?

7.
What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

8.
Which element has the largest number of stable isotopes?

9.
Who built the first mass spectrometer in Czechia?

10.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

Czech Museum
of Mass Spectrometry

Our partners

Mass Spectrometry Quiz

Mass Spectrometry Quiz

Thank you for taking our quiz!

1. Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:

2. Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

3. List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).

4. What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

5. Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?

6. Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?

7. What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

8. Which element has the largest number of stable isotopes?

9. Who built the first mass spectrometer in Czechia?

10. The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

Czech Museumof Mass Spectrometry

Our partners

1.
Until 2019, the kilogram unit was defined using an international prototype kept at the International Bureau of Weights and Measures in France. The International Prototype of the Kilogram was made of an alloy of platinum and one other metal. The metal was:

2.
Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

3.
List these compounds according to their increasing mass: hydrazine (H4N2), oxygen (O2), methanol (CH4O).

4.
What principle of positive ray detection was used in the first Thomson's parabola spectrographs?

5.
Who first reported the fragmentation after the gamma hydrogen rearrangement to an unsaturated group via a sixmembered intermediate?

6.
Joseph John Thomson (1856 - 1940), Nobel laureate in physics, is credited with the invention of the mass spectrometer, the discovery of the electron and isotopes of stable elements. A lesser-known fact is his father's profession. What was it?

7.
What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

8.
Which element has the largest number of stable isotopes?

9.
Who built the first mass spectrometer in Czechia?

10.
The quadrupole mass filter has been known since the mid-1950s thanks to the work of Wolfgang Paul. The motion of ions in a quadrupole field can be described by solving second-order differential equations. When were these equations solved mathematically?

Czech Museum
of Mass Spectrometry